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Published on: 28/05/2021
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Questions + Answers key
Take MCQ Chemistry Test1.
For a second order reaction 2A ⟶ Product, a plot t1/2 vs log a (a = initial conc.), what does the intercept represent?
2.
Consider the reaction 2A + B ⟶ Products. When concentration of B alone was doubled, half life time does not change. When conc. of A alone doubled, the rate increases by two times . What are the units of K and what is the order of reaction?
3.
What is the ratio of t3/4 : t1/2 for a first order reaction ?
4.
How is half-life period related to initial concentration for a second order reaction ?
5.
Can Mg reduce Al2O3 and Al reduces MgO? State the conditions required for this reduction process.
6.
During metallurgical process, in the extraction of metal, flux is added. Why?
7.
Which Substance is added to molten iron to remove sulphur impurity?
8.
What are the oxidation states of iron in Fe3O4?
1.
t1/2 = 1/k .1/[Ao]
log t1/2 = -log K – log [Ao]
Intercept = t1/2.
2.
The half life is independent of conc. of B. This means the reaction is of first order w.r.t. B and w.r.t. A also it is first order and overall order is second.
3.
2:1
4.
t1/2 ∝a1−n.
For n = 2, t1/2 ∝a−1,i.e.,
t1/2 ∝ 1a
Thus, half-life period of a order reaction is inversely proportional to the initial concentration of the reactant.
5.
( )
If we look at the Ellingham diagram, it becomes evident that the plots for Al and Mg cross each other at 1350∘C1350∘C (1623 K). Below this temperature, Mg can reduce Al2O3Al2O3 and above this temperature, Al can reduce MgO.
6.
( )
Flux in the smelting process is added to, decrease the solubility of impurities, increase the fusion temperature of roasted ore and convert impurities into slag.
Flux removes the gangue to form easily fusible slag.
\(\mathrm{SiO}_{2}+\ \ \ \mathrm{FeO} \rightarrow\ \ \ \mathrm{FeSiO}_{3}\)
Acidicflux Basicangue Slag
7.
( )
To satisfy low sulfur requirements for iron processed into steel, magnesium reagents in powder or granular form are used to remove sulfur via slag-liquid metal reactions done under reducing conditions, where sulfur is transferred out of the steel through the slag-metal interface, and into the slag.
8.
( )
\(\frac{8}{3}\) Fe3O4 is basically a mixture of Fe2O3 and FeO.
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