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Published on: 28/05/2021
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Questions + Answers key
Take MCQ Chemistry Test1.
How does NaCN act as a depressant in preventing zinc from forming the froth? Explain.
2.
The rate for a reaction between the substance A and B is given by Rate = k[A]n [B]m
On doubling the conc. of A and halving the conc. of B, find out the ratio of new rate to that of earlier rate of reaction.
3.
What are antihistamines ? Give two examples. Explain how ddo they act on the human body ?
4.
What problem arises in using alitame as artificial sweetener ?
5.
(a) NC13 get hydrolysed to form NH3 and HOCI while PCI3 on hydrolysis gives H3PO3 and HCI. Explain why ?
(b) SOCI2 can act as a weak acid as well as a weak base. Explain.
6.
What is the role of ZnCl2 in a dry cell?
7.
Iron changes its crystal structure from body-centred to cubic close-packed structure when heated to 9160C.Calculate the ratio of the bcc crystal to that of ccp crystal,assuming that the metallic radius of the atom does not change.
1.
ZnS forms soluble complex Na2 [Zn(CN)4] while PbS forms froth.
When the minerals are expected to contain PbS and ZnS, suitable depressants such as NaCN are added.
The added NaCN, selectively prevents ZnS from coming to the froth by forming soluble complex Na2[Zn(CN)4] and PbS is removed along with the froth.
2.
Earlier rate R = K[A]n [B]m
Now rate R1 = K[2A]n [B/2]m
R1/R = 2n-m
3.
The hypersensitivity of some persons towards certain drugs (penicillin, sulpha drugs), dust, pollen grains, cat fur, a particular food or fabric, etc. is called allergy. Allergy is caused by release of a substance called histamine in the body Antihistamines are drugs which either reduce or inhibit the action of histamine in the body thereby preventing allergy. Two important antihistamine or anti-allergic drugs are brompheniramine and terfenadine. .
Mode of action. Histamines interact with the binding sites of receptor in the body to produce allergy. Antihistamines compete with histamines for these binding sites of receptor and thus do not allow histamine to produce allergy. Thus, antihistamines are drugs which interfere with the natural action of histamine by competing for histamine binding sites of receptor.
4.
Alitame is a high potency artificial sweetener. Therefore, it is difficult to control the sweetness of the food to which it is added.
5.
(a) N does not have d-oribitals to accommodate the electrons donated by O of \({ H }_{ 2 }O\), therefore, attack of \({ H }_{ 2 }O\) occurs on the CI atom which has d- orbitals to accommodate the extra electrons donated by \({ H }_{ 2 }O\). Consequently Cl-O bond is formed leading to the formation of HOCl and NH3 as shown below:

In contrast, both P and CI have d-orbitals to accommodate electrons donated by \({ H }_{ 2 }O\). But P-O bond is much stronger than CI-O bond. As a result, attack of \({ H }_{ 2 }O\) molecules occurs preferentially on P of PCI3 to form H3PO3 and HCl.
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(b) The basic character of SOCI2 is due to the presence of a lone pair of electrons on the S-atom. Further, in SOCI2, S also has empty d- orbitals which can be used to accept electrons. Therefore, SOCI2 also behaves as a Lewis acid.
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6.
ZnCl2 combines with the NH3 produced to form the complex salt [Zn(NH3)2 Cl2] as otherwise the pressure developed due to NH3 would crack the seal of the cell.
7.
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