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Published on: 24/05/2021
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Questions + Answers key
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1.
Which one among the following is the strongest oxidizing agent? \(CIO^{-}_{4}, BrO^{-}_{4}, IO^{-}_{4}.\)
2.
Write the structure of a chalcogenide dianion.
3.
Why is white phosphorus kept under water ?
4.
Which of the following is/are not known ? PCl3, AsCl3, SbCl3, NCl5, BiCl5.
5.
Out of H2O and H2S, which one has higher bond angle and why?
6.
What causes Brownian movement in a colloidal solution?
7.
Benzaldehyde can be obtained from benzal chloride Write reactions for obtaining benzal chloride and then benzaldehyde from it.
8.
Name the central metal ion present in haemoglobin and vitamin B12.
9.
What type of bonding occurs in globular proteins ?
10.
Name the monosaccharide units in maltose.
11.
Which is the most common oxidation contraction ?
12.
Among octahedral and tetrahedral crystal fields, in which case the magnitude of crystal field splitting is larger ?
13.
The relative ease of dehydration of alcohols is : tertiary > secondary > primary
14.
________ is the branch of chemistry which deals with the treatment of diseases using chemicals.
1.
( )
Amongst \(CIO^{-}_{4}{E^o=+1.19 V}, BrO^{-}_{4}{E^o=+1.74 V}, IO^{-}_{4}{E^o=+1.65 V}, \ BrO^{-}_{4}\) has the highest electrode potential and hence it is the strongest oxidising agent.
2.
( )
O2-, S2- or Se2-, etc.
3.
( )
Due to angle strain and weaker forces of attraction, ignition temperature of white P is very low (303 K). Therefore, on exposure to air, it spontaneously catches fire forming P4O10. Therefore, to protect it protect it from air, it is kept under water.
4.
( )
(i) NCl5 (due to absence of d-orbitals)
(ii) BiCl5 (Bi5+ being an oxidising agent oxidises Cl- ion to Cl2 and Cl-ion being a reducing agent reduces Bi5+ to Bi 3+).
5.
( )
H2O has larger bond angle than H2S because oxygen is more electronegative than sulphur and there is more bond-pair, bond-pair repulsion of two O-H bonds.
6.
( )
It is due to unbalanced collision between colloidal particles and with the particles of dispersion medium.
7.
It is the commercial method for preparing benzaldehyde. Benzal chloride can be obtained by photochlorination of toluene i.e., chlorination of toluene in presence of sunlight.
Then, benzal chloride on heating with boiling water produces benzaldehyde as shown below.
8.
Haemoglobin __ Iron (Fe) and vitamin -B12 _ Cobalt (Co).
9.
van der Waals interactions, disulphide bridges, dipolar interactions (ionic) and hydrogen bonding.
10.
Two α−D glucose units.
11.
+3
12.
It is larger in case of octahedral crystal field \(x = {-b \pm \sqrt{b^2-4ac} \over 2a}\((\triangle_t=4/9\ \triangle_0\ or\ \triangle_0\ =\ 9/4\ \triangle_t).\)\)
13.
The dehydration of alcohols occurs through carbocation intermediates. Since the stability of carbocations decreases in the order 30 > 20 > 10. Therefore, dehydration of alcohols follows the same order, i.e., tertiary > secondary > primary.
14.
( )
Chemotherapy
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