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Published on: 25/05/2021
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Download CBSE Class 12th Standard CBSE Chemistry question papers, sample papers, important questions, and previous year solved papers in PDF format. Get free study materials, NCERT solutions, and exam preparation resources for Class 12th Standard CBSE Chemistry
Questions + Answers key
Take MCQ Chemistry Test

1.
Which of the following is/are not known ? PCl3, AsCl3, SbCl3, NCl5, BiCl5.
2.
Which is a stronger reducing agent, SbH3 or BiH3, and why?
3.
Which is least basic ? SbH3, PH3, NH3, ASH3 ?
4.
Which is least acidic ? SbH3, Ph3, NH3,AsH3
5.
Give reasons for the least rectivity of nitrogen molecule.
1.
( )
(i) NCl5 (due to absence of d-orbitals)
(ii) BiCl5 (Bi5+ being an oxidising agent oxidises Cl- ion to Cl2 and Cl-ion being a reducing agent reduces Bi5+ to Bi 3+).
2.
( )
As we move down the group 15 elements from Sb to Bi, the atomic size increase and hence the strength of the bond it makes with hydrogen decreases, i.e., Bi-H bond is weaker than Sb-H bond. In other words, BiH3 is thermally less stable than sbH3. Therefore, on heating, BiH3 has a greater tendency to liberate hydrogen than SbH3 is a stronger reducing agent than SbH3.
3.
( )
A compound which is most acidic is obviously least basic. Since SbH3 is most acidic, therefore, it is least basic. or As the size of the atom increases, electron density decreases and hence basicity decreases. Thus SbH3 is least basic.
4.
( )
A compound which is most basic is obviously least acidic. Since NH3 is the most basic compound, therefore, it is least acidic.
5.
( )
Due to presence of a triple bond between the two N-atoms, the bond dissociation enthalpy (941.4 kJ mol-1) is very high. Hence, N2 is least reactive.
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