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Published on: 27/11/2019
Alkali and Alkaline Earth Metals
Download Tamil Nadu 11th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
Questions + Answers key
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1.
Half life of francium is _______
12.3 years
12.3 mins
21 years
21 mins
2.
The radioactive element of group 1 is ______
rubidium
cesium
francium
radium
3.
Lithium shows diagonal relationship with _____________
sodium
magnesium
calcium
aluminium
4.
Which of the following compounds will not evolve H2 gas on reaction with alkali metals ?
ethanoic acid
ethanol
phenol
none of these
5.
For alkali metals, which one of the following trends is incorrect ?
Hydration energy: Li > Na > K > Rb
Ionisation energy: Li > Na > K > Rb
Density: Li < Na < K < Rb
Atomic size: Li < Na < K < Rb
6.
Mention the uses of lithium.
7.
Explain the following:
The second ionisation enthalpy values of alkali metals are high.
8.
Why alkali metals do not occur free in native?
9.
Write the chemical equations for the reactions involved in solvay process of preparation of sodium carbonate.
10.
Give the systematic names for the following
Milk of magnesia
11.
Why group 2 elements have positive electron gain enthalpy?
12.
List down the uses of washing soda
13.
List out the uses of alkali metals
14.
Why are potassium and caesium, rather than lithium used in photochemical cells?
15.
An alkali metal (x) forms a hydrated sulphate, X2SO4 • 10 H2O. Is the metal more likely to be sodium (or) potassium.
16.
How is plaster of paris prepared ?
17.
Discuss the similarities between beryllium and aluminium.
18.
The hydrides of alkali metals behave as strong reducing agents - Justify the statement.
19.
1.
(d)
21 mins
2.
(c)
francium
3.
(b)
magnesium
4.
(d)
none of these
5.
(c)
Density: Li < Na < K < Rb
6.
(i) Lithium metal is used to make alloys.
(ii) Lithium is also used to make electrochemical cells.
(iii) Lithium carbonate is used in medicines.
7.
The removal of an electron from the alkali metals gives monovalent cations having stable electronic configurations similar to the noble gas. Therefore, it becomes very difficult to remove the second electron from the stable configurations already attained. Hence, the second ionisation enthalpy values of alkali metals are high.
8.
Since ionisation energy values of alkali metals are low, they are very reactive. They readily combine with oxygen, moisture and CO2 of the atmosphere and form compounds. Hence they do not occur free in nature.
9.
2NH3 + H2O + CO2 ⟶ (NH4)2 CO3
(NH4)2 CO3 + H2O + CO2 ⟶ 2NH4 HCO3
2NH4HCO3 + NaCl ⟶ NH4Cl + NaHCO3
2NaH CO3 ⟶ Na2 CO3 + CO2 + H2O.
10.
Mg (OH)2 ; Magnesium hydroxide.
11.
Group 2 elements have positive electron gain enthalpy since they have fully filled s-subshell, they have the least tendency to accept electrons.
12.
(i) Sodium carbonate known as washing soda is used for laundering
(ii) It is an important laboratory reagent used in the qualitative analysis and in volumetric analysis.
(iii) It is also used in water treatment to convert the hard water to soft water
(iv) It is used in the manufacture of glass, paper, paint etc
13.
(i) Lithium metal is used to make useful alloys. For example with lead it is used to make 'white metal' bearings for motor engines, with aluminium to make aircraft parts, and with magnesium to make armour plates. It is used in thermonuclear reactions.
(ii) Lithium is also used to make electrochemical cells.
(iii) Lithium carbonate is used in medicines
(iv) Sodium is used to make Na/Pb alloy.
(v) Liquid sodium metal is used as a coolant in fast breeder nuclear reactors.
(vi) Potassium chloride is used as a fertilizer. Potassium hydroxide is used in the manufacture of soft soap. It is also used as an excellent absorbent of carbon dioxide.
(vii) Caesium is used in devising photoelectric cells.
14.
(i) Due to low ionisation energy K and Cs eject electrons when exposed to light.
(ii) Lithium which has highest ionisation enthalpy among alkali metals cannot be used in photoelectric cells because it does not release electrons when exposed to light
15.
In Na2 SO4.10 H2O. So the metal will be Na (sodium). The salt is washing soda.
16.
Calcium Sulphate (plaster of paris), CaSO4. 1/2H2O :
It is a hemihydrate of calcium sulphate. It is obtained when gypsum, CaSO4 .2H2O,is heated to 393 K
2(CaSO4.2H2O) ⟶ 2CaSO4,H2O + 3H2O
Above 393 K, no water of crystallisation is left and anhydrous calcium sulphate, CaSO4 is formed. This is a known 'dead burnt plaster'.
It has a remarkable property of setting with water. on mixing with an adequate quantity of water it forms a plastic mass that gets into hard solid in 5 to 15 minutes.
17.
| S.No | Properties |
|---|---|
| 1 | Beryllium chloride forms a dimeric structure like aluminium chloride with chloride bridges. Beryllitrm chloride also forms polymeric chain structure ln addition to dinner. Both are soluble in organic solvents and are strong lewis acids. |
| 2 | Beryllium hydroxide dissolves in excess of alkali and gives beryllate ion [Be(OH)2]2- as aluminium hydroxide which gives aluminate ion, [Al(OH)4]- |
| 3 | Beryllium arid aluminum ions have strong tendency to form complexes, |
| 4 | Both beryllium and aluminium hydroxides are amphoteric in nature. |
| 5 | Carbides of beryllium (Be2C) like aluminum carbide (Al4C3) give methane on hydrolysis |
| 6 | Both beryllium and aluminium are rendered passive by nitric acid |
18.
(i) All alkali metals react with hydrogen at about 673K (lithium at 1073K) to form the corresponding hydride which are ionic 10 nature.
(ii) Reactivity of alkali metals with hydrogen increases from Li to Cs
2M + H2 ⟶ 2M+H- (M= Li,Na,K,Rb,Cs)
(iii) Ionic character of the hydrides increases from Li to Cs.
(iv) The decrease in ionization enthalpy down the group permits easy availability of electrons to hydrogen, forming H+ ion.
(v) The hydrides behave as strong reducing agents and their reducing nature increases down the group.
19.
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