11th Standard Syllabus & Materials
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Published on: 19/08/2019
Alkali and Alkaline Earth Metals
Download Tamil Nadu 11th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
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1.
Which of the following dissolves in water with a hissing sound?
bleaching powder
marble
quick lime
slaked lime
2.
Lime water turning milky is due to the formation of ______
calcium carbonate
calcium hydroxide
calcium hydroxide
calcium chloride
3.
Alkaline earth metals form basic hydroxides. The metal hydroxide which is most basic is _____
Mg(OH)2
Ca(OH)2
Sr(OH)2
Ba(OH)2
4.
Electronic configuration of s-block elements is _______________
ns2
ns1
ns2np1
ns2np2
5.
Why Cs and K are used as electrodes in photoelectric cells ___________
Due to their less ionisation energy
Due to high ionisation energy
Due to diagonal relationship
None of these
6.
The reducing power of a metal depends on various factors. Suggest the factor. which makes Li, the strongest reducing agent in aqueous solution __________
Sublimation enthalpy
Ionisation enthalpy
Hydration enthalpy
Electron-gain enthalpy
7.
The hydration enthalpies of alkali metal ions decreases in ______ order.
Li+ > Na+ > K+ > Rb+ > Cs+
Cs+ > Rb+ > K+ > Na+ > Li+
Li+ > Rb+ > K+ > Na+ > Cs+
Rb+ > Cs+ > K+ > Na+ > Li+
8.
Which is the correct sequence of solubility of carbonates of alkaline earth metals ?
BaCO3 > SrCO3 > CaCO3 > MgCO3
MgCO3 > CaCO3 > SrCO3 > BaCO3
CaCO3 > BaCO3 > SrCO3 > BaCO3
BaCO3 > CaCO3 > SrCO3 > MgCO3
9.
Lithium shows diagonal relationship with _____________
sodium
magnesium
calcium
aluminium
10.
Which of the following compounds will not evolve H2 gas on reaction with alkali metals ?
ethanoic acid
ethanol
phenol
none of these
11.
Discuss the biological importance of sodium and potassium.
12.
Mention the uses of lithium.
13.
Explain why atomic and ionic radius increases from lithium to caesium?
14.
Explain what is meant by efflorescence.
15.
Why does Li2CO3 decompose at a temperature below 1273K?
16.
Account for the following Li2CO3 is considerably less stable and decomposes readily in contrast to other alkali carbonates
17.
List out the uses of alkali metals
18.
Lithium salts are more soluble than the salts of other metals of group 1. Justify.
19.
Why alkaline earth metals are harder than alkali metals.
20.
Mention the uses of plaster of paris
21.
Discuss the similarities between beryllium and aluminium.
22.
Explain the important common features of Group 2 elements.
23.
Which would you expect to have a higher melting point magnesium oxide or magnesium fluoride ? Explain your reasoning.
1.
(c)
quick lime
2.
(a)
calcium carbonate
3.
(d)
Ba(OH)2
4.
(a)
ns2
5.
(a)
Due to their less ionisation energy
6.
(c)
Hydration enthalpy
7.
(a)
Li+ > Na+ > K+ > Rb+ > Cs+
8.
(b)
MgCO3 > CaCO3 > SrCO3 > BaCO3
9.
(b)
magnesium
10.
(d)
none of these
11.
(i) Sodium and potassium ions maintain the ion balance and nerve impulse conduction.
(ii) Transport of sugar and amino acids into cells.
(iii) Potassium ions activate many enzymes, participate in the oxidation of glucose to produce ATP.
(iv) With sodium, potassium ion is responsible for the transmission of nerve signals.
(v) Sodium and potassium pump play an important role in transmitting nerve signals.
12.
(i) Lithium metal is used to make alloys.
(ii) Lithium is also used to make electrochemical cells.
(iii) Lithium carbonate is used in medicines.
13.
On moving down the group, there is an increase in the number of shells, as well as increase in nuclear charge. The force of attraction between the nucleus and the added electron decreases. Hence, ionic and atomic radii increases.
14.
Efflorescence is the spontaneous loss of water by a hydrated salt, which occurs when the aqueous vapor pressure of the hydrate is greater than the partial pressure of the water vapour in the air. This is the property of salts
Ex: Glauber's salt- Na2SO4·10H2O
Epsom salt - MgSO4·7H2O
15.
(i)\(Li_2CO_3+\xrightarrow{Δ}Li_2O+CO_2\)
(ii) This is presumably due to large size difference between Li+ and \(CO_2^{ -3}\) which makes the crystal lattice unstable and decomposes readily
16.
This is due to large size difference between Li+ and which makes the crystal lattice unstable
17.
(i) Lithium metal is used to make useful alloys. For example with lead it is used to make 'white metal' bearings for motor engines, with aluminium to make aircraft parts, and with magnesium to make armour plates. It is used in thermonuclear reactions.
(ii) Lithium is also used to make electrochemical cells.
(iii) Lithium carbonate is used in medicines
(iv) Sodium is used to make Na/Pb alloy.
(v) Liquid sodium metal is used as a coolant in fast breeder nuclear reactors.
(vi) Potassium chloride is used as a fertilizer. Potassium hydroxide is used in the manufacture of soft soap. It is also used as an excellent absorbent of carbon dioxide.
(vii) Caesium is used in devising photoelectric cells.
18.
The high solubility of lithium salts is due to strong solvation of small size Li+ ion
19.
Alkali metals have one eo in their outer most shell. Alkaline earth metals have 2 eo in their outer most shell. More valence electrons and more positively charged nucleii leads to greater opportunity for metallic bonding.
20.
The largest use of plaster of paris is in the building industry as well as plasters. It is used for immobilising the affected part of organ where there is a bone fracture or sprain. It is also employed in dentistry, in ornamental work and for making casts of statues and busts.
21.
| S.No | Properties |
|---|---|
| 1 | Beryllium chloride forms a dimeric structure like aluminium chloride with chloride bridges. Beryllitrm chloride also forms polymeric chain structure ln addition to dinner. Both are soluble in organic solvents and are strong lewis acids. |
| 2 | Beryllium hydroxide dissolves in excess of alkali and gives beryllate ion [Be(OH)2]2- as aluminium hydroxide which gives aluminate ion, [Al(OH)4]- |
| 3 | Beryllium arid aluminum ions have strong tendency to form complexes, |
| 4 | Both beryllium and aluminium hydroxides are amphoteric in nature. |
| 5 | Carbides of beryllium (Be2C) like aluminum carbide (Al4C3) give methane on hydrolysis |
| 6 | Both beryllium and aluminium are rendered passive by nitric acid |
22.
1. This group contains Be, Mg, Ca, Sr, Ba & Ra.
2. Except Be all these elements are called as alkaline earth metals because their oxides and hydroxides are alkaline in nature.
3. Beryllium is the rare element and Radium is the rarest (10% rocks) ; Their Occurrence: Be- Beryl; Mg - carnallite; Dolomite Ca - Fluorapatite; Sr - Celestite Ba - Barytes.
4. Radium is radioactive.
5. The general electronic configuration is :
[Noble gas] ns2 eg. Be - [He] 2s2
6. On moving down the group the radii increase. Their atomic radii are smaller than alkali metals.
7. They exhibit +2 oxidation state.
8. The ionisation enthalpies are less than p - block elements due to large size. Down the group the ionisation enthalpy decreases.
9. The IE1 of group 2 elements are greater than group 1 elements.
10. The IE2 values are higher than that of alkali metals.
11. They are less electro Positive elements than alkali metals.
12. The hydration enthalpy decreases with increase in ionic radii.
13. MgCl2 form MgCI2 .6H2O and CaCl2 form CaCl2.6H2O
14. The electronegativity value decreases down the group.
15. With concentrated HCl They impart flame colour. Ca - Brick Red ; Sr - Crimson red and Barium - Apple Green.
16. All form metallic halides at elevated temperatures. M + X2 + MX2
17. All elements except Beryllium combine with hydrogen to form hydrides of formula MH2.
23.
Magnesium oxide in having higher melting point. The lattice energy of MgO & MgF2 are 3938 and 2957 respectively.
MgO has +2, -2 charges, MgF2 has +2, -1 charges. When the two charges are multiplied together, MgO results in larger amount of lattice energy since it has a higher charge, The strong attraction cause most ionic material to be hard and brittle and have high melting points.
11th Standard Syllabus & Materials
11th Standard
TN 11th Tamil பீடு பெற நில் - செய்யுள் - காவடிச்சிந்து Important Questions And Answers Study Material - QB365 Set A
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