11th Standard Syllabus & Materials
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Published on: 25/06/2021
QB365 provides detailed and simple solution for every
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Download Tamil Nadu 11th Standard Chemistry question papers, model tests, one-mark questions, important questions, and public exam papers in PDF format. Free study materials and answer keys for TN State Board students.
Questions + Answers key
Take MCQ Chemistry Test1.
Balance the following equations by oxidation number method.
KMnO4 + KOH + H2O2 ⟶ K2MnO4 + O2 + H2O
2.
Balance the following equations by oxidation number method.
KBr + MnO2 + H2SO4 ⟶ KHSO4 + MnSO4 + H2O + Br2
3.
Balance the following equations by oxidation number method.
K2Cr2O7 + FeSO4 + H2SO4 ⟶ K2SO4 + Cr2(SO4)3 + Fe2(SO4)3 + H2O
4.
Balance the following equations by oxidation number method.
Ag + HNO3 ⟶ AgNO3 + H2O + NO
5.
Balance the following equations by oxidation number method.
Zn + HNO3 ⟶ Zn(NO3)2 + N2O + H2O
1.
Step - 1 : To find out atoms undergoing change in O.N.
\(\overset { +1+7-2 }{ KMnO_{ 4 } } +\overset { +1-2+1 }{ KOH } +\overset { +1-1 }{ { H }_{ 2 }{ O }_{ 2 } } \rightarrow +\overset { +1+6-2 }{ K_{ 2 }MnO_{ 4 } } +\overset { 0 }{ { O }_{ 2 } } +\overset { +1-2 }{ { H }_{ 2 }O } \)
Step - 2 : To find out total increase and decrease in O.N .
\(\overset { +7 }{ KMnO_{ 4 } } \rightarrow \overset { +6 }{ K_{ 2 }MnO_{ 4 } } \) (decrease of 1 unit per atom)
\(\overset { -1 }{ { H }_{ 2 }{ O }_{ 2 } } \rightarrow \overset { 0 }{ { O }_{ 2 } } \) (increase of 1 unit per atom or 2 units per atom)
Total increase = 2
Total decrease = 2
Step - 3 : To balance the total increase and decrease in O.N, multiply KMnO4 by 2.
2KMnO4 + KOH + H2O2 ⟶ K2MnO4 + O2 + H2O
Step - 4 : To balance all atoms other than 'H' and 'O'
2KMnO4 + 2KOH + H2O2 ⟶ 2K2MnO4 + O2 + H2O
number of oxygen atoms on LHS = 12
number of oxygen atoms on RHS = 11
Hence, multiply H2O in RHS by 2. The equation becomes,
2KMnO4 + 2KOH + H2O2 ⟶ 2K2MnO4 + O2 + H2O
Hydrogen atoms balance by themselves. The balanced equation is
2KMnO4 + 2KOH + H2O2 ⟶ 2K2MnO4 + O2 + 2H2O
2.
Step - 1 : To find atoms undergoing change in O.N.
\(\overset { +1-1 }{ KBr } +\overset { +4-2 }{ MnO_{ 2 } } +\overset { +1+6-2 }{ { H }_{ 2 }SO_{ 4 } } \rightarrow +\overset { +1+1+6-2 }{ KHSO_{ 4 } } +\overset { +2+6-2 }{ MnSO_{ 4 } } +\overset { -1-2 }{ { H }_{ 2 }O } +\overset { 0 }{ { Br }_{ 3 } } \)
Step - 2 : To find the total increase and decrease
\(\overset { +4 }{ MnO_{ 4 } } \rightarrow \overset { +2 }{ MnSO_{ 4 } } \) (Decrease in O.N. of 2 units per atom)
KBr-1Br2 (increase in O.N. of I unit per atom)
Total decrease = 2 x 1 = 2
Total increase = 1 x 2 = 2
Step - 3 : To balance the total increase and decrease in O.N, multiply KBr by 2.
2KBr + MnO2 + H2SO4 ⟶ KHSO4 + MnSO4 + H2O + Br2
Step - 4 : To balance all atoms other than hydrogen and oxygen atoms
2KBr + MnO2 + H2SO4 ⟶ 2KHSO4 + MnSO4+ H2O + Br2
Since SO4-2 (sulphate) radical does not undergo any change in O.N.
balance them RHS = 3 (SO42) radical; RHS = I (SO4-2)
Hence multiply H2SO4 in LHS by 3. The equation now becomes
2KBr + MnO2 + 3H2SO4 ⟶ 2KHSO4 + MnSO4 + H2O + Br2
To balance 'O' atoms, multiply H2O in RHS by 2.
2KBr + MnO2 + 3H2SO4 ⟶ 2KHSO4 + MnSO4 + 2H20 + Br2
This is the balanced equation.
3.
Step-1: To find out atoms undergoing change in O.N.
\(\overset { +1+6-2 }{ { K }_{ 2 }{ Cr }_{ 2 }{ O }_{ 7 } } +\overset { +1+6-2 }{ { H }_{ 2 }SO_{ 4 } } +\overset { +2+6-2 }{ Fe{ SO }_{ 4 } } \rightarrow \overset { +1+6-2 }{ { K }_{ 2 }{ SO }_{ 4 } } +\overset { +3\quad \quad +6-2 }{ { Cr }_{ 2 }(SO_{ 4 })_{ 3 } } +\overset { +3\quad \quad +6-2 }{ { Fe }_{ 3 }({ SO }_{ 4 })_{ 3 } } +\overset { +1-2 }{ { H }_{ 2 }O } \)
Step-2: To find out totel increase and decrease in O.N.
\(\overset { +6 }{ { K }_{ 2 }{ Cr }_{ 2 }{ O }_{ 7 } } \rightarrow \overset { +3 }{ { Cr }_{ 2 }({ SO }_{ 4 }) } _{ 3 }\) (Decrease of 3 unit / atom; 6 unit / 2 atoms)
Total decrease = 6 units
\(\overset { +2 }{ Fe_{ 2 }{ SO }_{ 4 } } \rightarrow \overset { +3 }{ { Fe }_{ 2 }({ SO }_{ 4 })_{ 3 } } \) (increase of 1 unit / atom
Total increase 1 x 6 = 6
Step-3: To balance the total increase and total decrease, multiply FeSO4 by 6.
K2Cr2O7 + 6FeSO4 +H2SO4 ⟶ K2SO4 + Fe2(SO4)3 + Cr2(SO4)3 + H2O
Step-4: Balance all atoms other than 'H' and 'O'.
Since Fe is oxidised (LHS) to Fe+3 (RHS) balance Fe2(SO4)3 by multiplying by 3.
Now the equation becomes,
K2Cr2O7 + 6FeSO4 + H2SO4 ⟶ K2SO4 + Cr2(SO4)3 + 3Fe2(SO4)3 + H2O
The sulphur atoms in SO4-2 radical does not undergo any change in O.N.
There are 7, SO4-2 radicals in LHS and 13, SO4-2 radicals in RHS.
To balance them, multiply H2SO4 in LHS by 7. The equation now becomes.
K2Cr2O7 + 6FeSO4 + 7H2SO4 ⟶ K2SO4 + Cr2(SO4)3 + 3Fe2(SO4)3 +H2O.
4.
Step - 1 : To balance atoms undergoing change in O.N.
\(\overset { 0 }{ Ag } +\overset { +1+5-2 }{ HNO_{ 3 } } \rightarrow +\overset { +1+5-2 }{ AgNO } +\overset { +1-2 }{ { H }_{ 2 }O+ } \overset { +2-2 }{ NO } \)
Step - 2 : To find out total increase and decrease in O.N.
\(\overset { 0 }{ Ag } \rightarrow \overset { +1 }{ Ag(NO_{ 3 })_{ 2 } } \) (increase of 1 unit / atom)
\(\overset { +5 }{ AgNO3 } \rightarrow +\overset { +2 }{ NO } \) (decrease of 3 units / atom)
Total increase = 1 x 3 = 3
Total decrease = 3 x 1 = 3
Step - 3 : To balance the total increase and decrease in O.N, multiply Ag by 3.
3Ag + HNO ⟶ AgNO3 + H2O +NO
Step - 4 : To balance all atoms other than hydrogen and oxygen.
3Ag + 4HNO3 ⟶ 3AgNO3 + H2O + NO
Step - 5 : To balance oxygen atoms
3Ag + 4HNO3 ⟶ 3AgNO3 + 2H2O + NO
Hydrogen atoms balanced by themselves.
The balanced equation is 3Ag + 4HNO3 ⟶ 3AgNO3 + 2H2O + NO
5.
Step - 1 : To find out atoms undergoing change in O.N.
\(\overset { 0 }{ Zn } +\overset { +1+5-2 }{ HNO_{ 3 } } \rightarrow +\overset { +2+6-2 }{ Zn(NO_{ 3 })_{ 2 } } +\overset { +1-2 }{ { N }_{ 2 }O } +\overset { +1-2 }{ { H }_{ 2 }O } \)
Step - 2 : To find out the total increase and decrease in O.N.
\(\overset { 0 }{ Zn } \rightarrow \overset { +2 }{ Zn } \) (NO3)2 (increase of 2 units per atom)
\(\overset { +5 }{ HNO_{ 3 }\rightarrow } \overset { +1 }{ { N }_{ 2 }O } \) (decrease of 4 units per atom)
Total increase 2 x 4 = 6
Total decrease 4 x 2 = 6
Step - 3 : To balance the total increase and decrease in O.N.
4Zn + 2HNO3 ⟶ Zn(NO3)2 + N2O + 5H2O
Step - 4 : Balance the equation
4Zn + 2HNO3 ⟶ 4Zn(NO3)2 + N2O + 5H2O
'8' nitrogen atoms, 12 oxygen atoms '8' hydrogen atoms in RHS to be balanced.
For this add 8 HNO3 to LHS.
4Zn + 10HNO3 ⟶ 4Zn(NO3)2 + N2O + 5H2O
The equation is now balanced.
11th Standard Syllabus & Materials
11th Standard
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