(i) (CCI₃)₃ CCl
2-(trichloromethyl)- 1,1,1,2,3,3,3-hepta chloropropane
(ii) (CH₃)₃ CCH = C(CI) C₆H₄I- p

1-Chloro -1-(4-iodophenyl)-3,3-dimethylbut-l-ene.

Carbylamine reaction:
Chloroform reacts with aliphatic or aromatic primary amine and alcoholic caustic potash, to give foul smelling alkyl isocyanide (carbylamines).

This reaction is used to test primary amine.

Fluoro benzene is prepared by treating benzene diazonium chloride with fluoro boric acid. This reaction produces diazoriium fluoroborate which on heating produces fluorobenzene. This reaction is called Balz - Schiemann reaction.
\(\underset { Benzene\ diazonium \ chloride }{ { C }_{ 6 }{ H }_{ 5 }{ N }_{ 2 }Cl } +HB{ F }_{ 4 }\overset { \longrightarrow }{ -HCl } { C }_{ 6 }{ H }_{ 5 }{ N }_{ 2 }BF\overset { \longrightarrow }{ heat } \underset { Fluorobenzene }{ { C }_{ 6 }{ H }_{ 5 }F+{ BF }_{ 3 }+{ N }_{ 2 } } \)

Haloalkane reacts with active metals like sodium, lead etc in the presence of dry ether to form organo metallic compounds.
\(\underset { Ethylbromide }{ { CH }_{ 2 }{ CH }_{ 2 }Br+2Li } \overset { Dryether }{ \longrightarrow } \underset { Ethyl\quad Lithium }{ { CH }_{ 2 }Li+LiBr } \)
\(\underset { Ethyl\quad bromide }{ 4C{ H }_{ 3 }{ CH }_{ 2 }Br } +\underset { Sodium-lead\quad alloy }{ 4Na/pb } \longrightarrow \underset { Tetra\quad ethyl\quad lead(TEL) }{ ({ CH }_{ 3 }{ CH }_{ 2 })4pb+4NaBr+3pb } \)

When a haloalkene containing a hydrogen on \(\beta\) carbon is treated with an ethanolic solution of potassium hydroxide, an alkene is formed. In this reaction a double bond between and \(\beta\) carbon is formed by releasing a halogen attached to a carbon and a hydrogen to a carbon of halo alkane, is reaction is called elimination reaction. (dehydrohalogenation).
CH₃ CH₂ Br + KOH \(\overset { ethanol }{ \longrightarrow } \)CH₂ = CH₂ + KBr + H₂O