11th Standard Syllabus & Materials
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TN 11th Tamil பீடு பெற நில் - துணைப்பாடம் - வாடிவாசல் Important Questions And Answers Study Material - QB365 Set A
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TN 11th Tamil பீடு பெற நில் - செய்யுள் - குறுந்தொகை Important Questions And Answers Study Material - QB365 Set A

Published on: 13/05/2022
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Questions + Answers key
Take MCQ Chemistry Test1.
How is hydrogen peroxide prepared on industrial scale?
2.
Explain about the structure of CuSO4.5H2O
3.
How does water react with
(i) SiCI4
(ii) P4O10
4.
How are reducing agents in synthetic organic chemistry prepared?
5.
Explain about Hydrogen sponge
1.
On an industrial scale, hydrogen peroxide is prepared by auto oxidation of 2-alkyl anthraquinol.
2.
Copper sulphate pentahydrate CuSO4.5H2O. In this compound, 4 water molecules form coordinate bonds while the fifth water molecule present outside the coordination can form intermolecular hydrogen bond with another molecule as [CU(H2O)4]SO4.H2O.
3.
(i) Water reacts with SiCl4 to give silica.
SiCl4 + 4H2O ⟶ Si(OH)4 + 4HCI
Si(OH)4 \(\overset { \Delta }{ \longrightarrow } \) SiO2 + 2H2O
Silica
(ii) Water reacts with P4010 to give orthophosphoric acid.
P4O10 + 6H2O ⟶ 4H3PO4
Orthophosphoric acid
4.
Hydrogen has a tendency to react with reactive metals like lithium, sodium to give corresponding hydrides.
2 Li + H2 ⟶ 2 LiH
2 Na + H2 ⟶ 2 NaH
These hydrides are used as reducing agents in synthetic organic chemistry. It is also used to prepare important hydrides such as lithium aluminium hydride and sodium boro hydride (organic reducing agents).
4 LiH + AICl3 ⟶ Li[AlH4] + 3 LiCI
4 NaH + B(OCH3)3 ⟶ Na[BH4] + 3CH3ONa
5.
(i) Hydrogen sponge (or) Metal hydride e.g., palladium-hydrogen system is a binary hydride (PdH).
(ii) Upon heating, H atoms diffuse through the metal to the surface and recombine to form molecular hydrogen. Since no other gas behaves this way with palladium, this process has been used to separate hydrogen gas from other gases:
2 Pd(s) + H2(g) \(\rightleftharpoons \) 2PdH(s)
(iii) The hydrogen molecule readily adsorb on the palladium surface, where it dissociates into atomic hydrogen. The dissociated atoms dissolve into the interstices or voids (octahedral or tetrahedral) of the crystal lattice.
(iv) Technically, the formation of metal hydride is by chemical reaction but it behaves like a physical storage method, i.e., it is absorbed and released like a water sponge. Such a reversible uptake of hydrogen in metals and alloys is also attractive for hydrogen storage and for rechargeable metal hydride battery applications.
11th Standard Syllabus & Materials
11th Standard
TN 11th Tamil பீடு பெற நில் - செய்யுள் - காவடிச்சிந்து Important Questions And Answers Study Material - QB365 Set A
NEW11th Standard
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NEW11th Standard
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NEW11th Standard
TN 11th Tamil மாமழை போற்றுதும் - செய்யுள் - ஐங்குறுநூறு Important Questions And Answers Study Material - QB365 Set A
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