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11th Standard English Medium Chemistry Subject Thermodynamics Book Back 5 Mark Questions with Solution Part - I

11th Standard

    Reg.No. :
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Chemistry

Time : 00:30:00 Hrs
Total Marks : 25

    Part I

    5 x 5 = 25
  1. Calculate the work done when 2 moles of an ideal gas expands reversibly and isothermally from a volume of 500 ml to a volume of 2 L at 25°C and normal pressure.

  2. Calculate the standard heat of formation of propane, if its heat of combustion is -2220.2 kJ mol-1. the heats of formation of CO2(g) and H2O(l) are -393.5 and -285.8 kJ mol-1 respectively

  3. For the reaction Ag2O(s) ⟶2Ag(s) + \(\frac{1}{2}\)O2(g) : ΔH =30.56 kJ mol-1 and AS = 6.66JK-1 mol-1 (at 1 atm). Calculate the temperature at which ΔG is equal to zero. Also predict the direction of the reaction (i) at this temperature and (ii) below this temperature.

  4. Calculate the enthalpy change for the reaction
    Fe2O3 + 3CO ⟶ 2Fe + 3CO2 from the following data.
    2Fe +\(\frac{3}{2}\)O2 ⟶ Fe2O3; ΔH = -741 kJ
    C +\(\frac{1}{2}\)O2 ⟶ CO; ΔH = -137 kJ 
    C + O2 ⟶ CO2; ΔH = - 394.5 kJ

  5. A gas mixture of 3.67 lit of ethylene and methane on complete combustion at 25°C and at 1 atm pressure produce 6.11 lit of carbondioxide. Find out the amount of heat evolved in kJ, during this combustion. (ΔHc(CH4)= - 890 kJ mol-1 and (ΔHc(C2H4) = -1423 kJ mol-1

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