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Ionic Equilibrium 3 Mark Book Back Question Paper With Answer Key

12th Standard

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Chemistry

Time : 01:30:00 Hrs
Total Marks : 72

    3 Marks 

    24 x 3 = 72
  1. The concentration of hydroxide ion in a water sample is found to be 2.5 × 10-6M. Identify the nature of the solution.

  2. A lab assistant prepared a solution by adding a calculated quantity of HCl gas 250C to get a solution with [H3O+] = 4\(\times\)10-5M. Is the solution neutral (or) acidic (or) basic.

  3. Calculate the pH of 0.04 M HNO3 Solution.

  4. Define ionic product of water. Give its value at room temperature.

  5. Explain common ion effect with an example.

  6. Calculate the pH of 1.5\(\times\)10-3 M solution of Ba(OH)2

  7. 50ml of 0.05M HNO3 is added to 50ml of 0.025M KOH. Calculate the pH of the resultant solution.

  8. The Ka value for HCN is 10-9. What is the pH of 0.4M HCN solution?

  9. Calculate the extent of hydrolysis and the pH of 0.1 M ammonium acetate Given that \(K_{a}=K_{b}=1.8\times10^{-5}\)

  10. Derive an expression for the hydrolysis constant and degree of hydrolysis of salt of strong acid and weak base.

  11. Solubility product of Ag2CrO4 is \(1\times10^{-12}\). What is the solubility of Ag2CrO4 in 0.01M AgNO3 solution?

  12. Write the expression for the solubility product of Ca3(PO4)2

  13. A saturated solution, prepared by dissolving CaF2(s) in water, has \([Ca^{2+}]=3.3\times10^{-4}M\). What is the Ksp of CaF2?

  14. A particular saturated solution of silver chromate Ag2CrO4 has \([Ag^{+}]=5\times10^{-5}\) and \([CrO_{4}]^{2-}=4.4\times10^{-4}M\). What is the value of Ksp for Ag2 CrO4?

  15. Write the expression for the solubility product of Hg2Cl2 .

  16. Ksp of Ag2CrO4 is \(1.1\times10^{-12}\). What is solubility of Ag2CrO4 in 0.1M K2CrO4.

  17. Will a precipitate be formed when 0.150 L of 0.1M Pb(NO3)2 and 0.100L of 0.2 M NaCl are mixed? \(K_{sp}\ (PbCl_{2})=1.2\times10^{-5}\).

  18. Ksp of Al(OH)3 is 1\(\times\)10-15M. At what pH does 1.0×10-3M Al3+ precipitate on the addition of buffer of NH4Cl and NH4OH solution?

  19. Calculate pH of 10-7 M HCl

  20.  Find the pH of a buffer solution containing 0.20 mole per litre sodium acetate and 0.18 mole per litre acetic acid. Ka for acetic acid is \(1.8\times10^{-5}\).

  21. What is the pH of an aqueous solution obtained by mixing 6 gram of acetic acid and 8.2 gram of sodium acetate and making the volume equal to 500 ml. (Given: Ka for acetic acid is  \(1.8\times10^{-5}\))

  22. Calculate i) degree of hydrolysis, ii) the constant hydrolysis  and iii) pH of 0.1M CH3COONa solution (pKa for CH3COOH is 4.74).

  23. Establish a relationship between the solubility product and molar solubility for the following
    a) BaSO
    b) Ag2(CrO4)

  24. Indicate find out whether lead chloride gets precipitated or not when 1 mL of 0.1M lead nitrate and 0.5 mL of 0.2 M NaCl solution are mixed? Ksp of PbCl2 is 1.2 x 10-5 .

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