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Hydroxy Compounds and Ethers 5 Mark Creative Question Paper With Answer Key

12th Standard

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Chemistry

Time : 02:30:00 Hrs
Total Marks : 75

     5 Marks

    15 x 5 = 75
  1. An organic compound (A) of molecular formula C3H8O gives turbidity within 5-10 min on reaction with anhydrous ZnCI2/HCI.Compound (A) on treatment with sodium hypochlorite gives a carbonyl compound (B) which on further chlorination gives compound (C) of molecular formula C3H3OCl3. Identify (A), (B) and (C). Explain the reactions.

  2. An organic compound (A) C2H6O liberates hydrogen on treatment with metallic sodium. (A) on mild oxidation gives (B) C2H4O which answers iodoform test. (B) when treated with cone. H2SO4 undergoes polymerisation to give (C) a cyclic compound. Identify (A) (B) and (C) and explain the reactions.

  3. An organic compound A of molecular f formula C6H6O gives violet colouration with neutral FeCl3. Compound A on treatment with metallic Na gives compound B. Compound B on treatment with CO2 at 400 K under pressure gives C. This product on acidification gives compound D (C7H6O3) which is used in medicine. Identify (A) (B) (C) and D and explain the reactions.

  4. An organic compound A of molecular formula C3H6O on reduction with LiAlH4 gives B. Compound B gives blue colour in Victor Meyer's test and also forms a chloride C with SOCl2. The chloride on treatment with alcoholic KOH gives D. Identify A, B, C and D and explain the reactions.

  5. Ail organic compound (A) C3H8O answers Lucas test within 5-10 minutes and on oxidation forms B (C3H6O). This on further oxidation forms C(C2H4O2) which gives effervescence with Na2 COBalso undergoes iodoform reaction. Identify A, B and C. Explain the conversion of A to B and C.

  6. Compound A of molecular formula C7His treated with chlorine and then with NaOH to get compound B of molecular formula C7H8O. B on oxidation by acidified K2Cr2O7 gives compound C of molecular formula C7H6O. Compound C on treatment with 50% caustic soda gives the compound B and also D. Find A, B, C and D. Explain the reactions.

  7. An organic compound (A) C3H8O answers Lucas test within 5-10 min and on oxidation forms (B) C3H6O. (B) on further oxidation forms (C) C2H4O2 which gives effervescence with NaHCO(B) also undergoes iodoform reactions. Identify A, B, C. Explain the reactions involved.

  8. Compound (A) of molecular formula C3H8O liberates hydrogen with sodium metal. (A) with P/I2 gives (B). Compound (B) on treatment with silver nitrite gives (C) which gives blue colour with nitrous acid. Identify (A), (B), (C) and explain the reactions.

  9. An organic compound (A) (C6H6O) gives maximum of two isomers (B) and (C) When an alkaline solution of (A) is refluxed with chloroform. (B) on oxidation gives acid (D). The acid (D) is also obtained by I treating sodium salt of (A) with CO2 under pressure followed by hydrolysis. Identify the compounds (A), (B), (C) and (D) and explain with proper chemical reactions.

  10. An organic compound A (C2H6O) liberates hydrogen with sodium metal. A when heated with alumina at 620 K gives an alkene B which when passed through Bayer's reagent gives C(C2H6O2). C reacts with PI3 and gives back B. Identify A, B and C. Write the reactions.

  11. An aromatic hydrocarbon A reacts with propene in the presence of anhydrous AlCl3 to give a compound B with a molecular formula C9H12 Further compound B undergoes oxidation in the, presence of air to give hydrogen peroxide C. Compound C decomposes in HCI acid solution to give compound D and acetone. Identify A, B, C and D. Explain the reactions.

  12. An organic compound A (C2H6O2) liberates hydrogen with metallic sodium. Compound A when heated with anhydrous zinc chloride ultimately gives B (C2H4O) whereas) when heated with cone. phosphoric acid gives C (C4H10O3). A on oxidation with acidified K2Cr2Ogives compound D (CH2O2). Identify A, B, C and D. Explain the reactions involved.

  13. What is major product formed when 3,3-dimethyl-2-butanol is heated in the presence of H2SO4.

  14. Explain the mechanism involved in the intermolecular dehydration of alcohols to give ethers.

  15. Explain auto-oxidation of ether.

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