Of the following compounds, which has the highest boiling point?

(a)

n-Butyl chloride

(b)

Isobutyl chloride

(c)

t-Butyl chloride

(d)

n-propyl chloride

C -X bond is strongest in __________

(a)

Chloromethane

(b)

Iodomethane

(c)

Bromomethane

(d)

Fluoromethane

Benzene reacts with Cl₂ in the presence of FeCl₃ and in absence of sunlight to form ________

(a)

Chlorobenzene

(b)

Benzyl chloride

(c)

Benzal chloride

(d)

Benzene hexachloride

Assertion: In mono haloarenes, electrophilic substitution occurs at ortho and para positions.
Reason: Halogen atom is a ring deactivator.
Codes:
(i) If both assertion and reason are true and reason is the correct explanation of assertion.
(ii) If both assertion and reason are true but reason is not the correct explanation of assertion.
(iii) If assertion is true but reason is false.
(iv) If both assertion and reason are false.

(a)

If both assertion and reason are true and reason is the correct explanation of assertion

(b)

If both assertion and reason are true but reason is not the correct explanation of assertion

(c)

If assertion is true but reason is false

(d)

If both assertion and reason are false

Freon-12 is manufactured from tetrachloro methane by ____________

(a)

Wurtz reaction

(b)

Swarts reaction

(c)

Haloform reaction

(d)

Gattermann reaction

The carbo cation formed in SN¹ reaction of alkyl halide in the slow step is ________

(a)

sp³ hybridised

(b)

sp² hybridised

(c)

sp hybridised

(d)

none of these

Which one of the following is most reactive towards nucleophilic substitution reaction?

(a)

(b)

(c)

(d)

Hunsdiecker reaction is used to prepare alkyl chloride and alkyl bromide starting from

(a)

diazonium salt

(b)

silver salts of carboxylic acid

(c)

sodium salt of carboxylic acid

(d)

alcohol

\({ CH }_{ 3 }-{ CH }_{ 3 }-Br\overset { KCN }{ \longrightarrow } X\overset { dil.HCl }{ \underset { \triangle }{ \longrightarrow } } Z\) Z is

(a)

CH₃CH₂COOH

(b)

CH₃COOH

(c)

CH₃COCI

(d)

CH3CONH2

Which of the following does not form grignard reagent on reaction with Mg in the presence of ether?

(a)

Chloro ethane

(b)

1 - Chluro propane

(c)

Vinyl chloride.

(d)

Bromo benzene

Which of the following is secondary alkyl halide?

(a)

Iso butyl chloride

(b)

Isopentyl chloride

(c)

Neopentyl chloride

(d)

Isopropyl chloride

Which ofthe following halogen exchange reaction will occur in acetone?

(a)

R-I +NaCI

(b)

R-F + KCI

(c)

R-CI +NaI

(d)

R- F +AgBrv

Grignard reagent is prepared by between___________.

(a)

Zin and alkyl halide

(b)

Magnesium and alkyl halide

(c)

Magnesium and alkane

(d)

Copper and aromatic hydrocarbon

Statement I : Primary alkyl halides on oxidation with DMSO gives aldehydes.
Statement II : DMSO is used as polar aprotic solvent.

(a)

Both statement I and statement II are true individually and statement II explains statement

(b)

Both statement I and statement II are true individually but statement II does not explain statement 1.

(c)

Only statement Iis true, but statement II is false.

(d)

Both statement I and II are false

\({ H }_{ 3 }C-\overset { \underset { | }{ { C }_{ 2 }{ H }_{ 5 } } }{ \underset { \overset { | }{ { C }_{ 3 }{ H }_{ 7 } } }{ C } } -Cl+\overset { \ominus }{ OH } \overset { S{ N }_{ 1 } }{ \longrightarrow } { H }_{ 3 }C-\overset { \underset { | }{ { C }_{ 2 }{ H }_{ 5 } } }{ \underset { \overset { | }{ { C }_{ 3 }{ H }_{ 7 } } }{ C } } -OH+\overset { \ominus }{ Cl } \)
What is the stereo chemistry ofthe above reaction?

(a)

complete racimisation

(b)

complete inversion

(c)

maximum inversion with partial racemisation

(d)

maximum racemisation with partial inversion

For reacting with HCI, the alcohol which does not require ZnCI₂ is ___________

(a)

PCl₃

(b)

PCl₅

(c)

SOCl₂

(d)

None of the above

Match the list I with list II and select the correct answer using the code given below the lists

List-I		List-II
A	Chloromycetin	1	Malaria
B	Thyroxine	2	Typhoid Fever
C	Chloroquine	3	Anaesthetic
D	Halothane	4	Goitre

(a)

	A	B	C	D
a	1	2	3	4

(b)

	A	B	C	D
a	3	1	4	2

(c)

	A	B	C	D
a	2	3	1	4

(d)

	A	B	C	D
a	4	2	3	1

How does dizzonium salt (C₆H₅N₂+Cl^-) decompose?

(a)

C₆HSCI+N₂

(b)

C₆H₅Br + N₂

(c)

only b

(d)

both a& b

The order of stability of the carbonium ion is__________.

(a)

1°> 2°>3°

(b)

2°> 3°>1°

(c)

2°> 1°>3°

(d)

3°>2°>1^o

Chlorebenzene reacts with CuCN at 523K in the presence of _____________.

(a)

NaOH

(b)

Pyrrole

(c)

Pyridine

(d)

Na