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Physical and Chemical Equilibrium Model Question Paper

11th Standard

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Chemistry

Time : 02:00:00 Hrs
Total Marks : 60
    7 x 1 = 7
  1. If Kb and Kf for a reversible reactions are 0.8 x 10–5 and 1.6 x 10–4 respectively, the value of the equilibrium constant is __________

    (a)

    20

    (b)

    0.2 x 10-4

    (c)

    0.05

    (d)

    none of these

  2. The equilibrium constant for a reaction at room temperature is K1 and that at 700 K is K2. If K1 > K2, then _____________

    (a)

    The forward reaction is exothermic

    (b)

    The forward reaction is endothermic

    (c)

    The reaction does not attain equilibrium

    (d)

    The reverse reaction is exothermic

  3. An equilibrium constant of 3.2\(\times\)10–6 for a reaction means, the equilibrium is _____________

    (a)

    largely towards forward direction

    (b)

    largely towards reverse direction

    (c)

    never established

    (d)

    none of these

  4. Equimolar concentrations of H2 and I2 are heated to equilibrium in a 1 litre flask. What percentage of initial concentration of Hhas reacted at equilibrium if rate constant for both forward and reverse reactions are equal ____________

    (a)

    33%

    (b)

    66%

    (c)

    (33)2%

    (d)

    16.5%

  5. For the formation of Two moles of SO3(g) from SO2 and O2, the equilibrium constant is K1. The equilibrium constant for the dissociation of one mole of SO3 into SO2 and O2 is __________

    (a)

    \(1/K_1\)

    (b)

    \(K_1^2\)

    (c)

    \(({1\over K_1})^{1/2}\)

    (d)

    \({K_1\over 2}\)

  6. For reaction, \(2A+B\rightleftharpoons 2C,\ K=x\) . Equilibrium constant for \(C\rightleftharpoons A+1/2B\) will be ____________

    (a)

    x

    (b)

    \(\cfrac { x }{ 2 } \)

    (c)

    \(\cfrac { 1 }{ \sqrt { x } } \)

    (d)

    \(\sqrt { x } \)

  7. In the equilibrium reaction CaCO3(s)⇌ CaO(s) + CO2(g) whose concentration remains constant at a given temperature?

    (a)

    CaO

    (b)

    CO2

    (c)

    CaCO3

    (d)

    Both (a) and (c)

  8. 9 x 2 = 18
  9. What is the relation between KP and KC. Give one example for which KP is equal to KC.

  10. State Le-Chatelier principle.

  11. State law of mass action.

  12. Derive a general expression for the equilibrium constant KP and KC for the reaction 
    3H2(g) + N2(g) ⇌ 2NH3(g).

  13. What is the effect of added inert gas on the reaction at equilibrium at constant volume.

  14. Deduce the Vant Hoff equation.

  15. Write the relationship between equilibrium constant and enthalpy.

  16. "Rate of Melting = Rate of freezing"
    When is the above condition achieved? Explain with an example

  17. 5 x 3 = 15
  18. The value of Kc for the reaction
    N2O2(g) \(\rightleftharpoons \) 2NO2(g)

  19. One mole of PCl5 is heated in one litre closed container. If 0.6 mole of chlorine is found at equilibrium, calculate the value of equilibrium constant.

  20. Oxidation of nitrogen monoxide was studied at 200o C with initial pressures of 1 atm NO and 1 atm of O2. At equilibrium partial pressure of oxygen is found to be 0.52 atm calculate KP value.

  21. List out few examples of irreversible reactions (changes) taking place in our daily life activity.

  22. Mention the applications of equilibrium constant

  23. 4 x 5 = 20
  24. The atmospheric oxidation of NO
    2NO(g) + O2(g) ⇌ 2NO2(g)
    was studied with initial pressure of 1 atm of NO and 1 atm of O2. At equilibrium, partial pressure of oxygen is 0.52 atm calculate Kp of the reaction.

  25. 28 g of Nitrogen and 6 g of hydrogen were mixed in a 1 litre closed container. At equilibrium 17 g NH3 was produced. Calculate the weight of nitrogen, hydrogen at equilibrium.

  26. Derive the Kp and Kc for the following equilibrium reaction.
    \({ H }_{ 2\left( g \right) }+{ I }_{ 2\left( g \right) }\rightleftharpoons { 2HI }_{ \left( g \right) }\)

  27. Explain the effect of concentration, pressure, temperature, catalyst and inert gas on equilibrium.

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